| Place | Player | Matches | Goals | Penalties | First match | Last match |
|---|---|---|---|---|---|---|
| 1 | Julio Cesar | 17 | 0 | 0 | 2004-09-08 | 2013-07-01 |
| 2 | Dani Alves | 14 | 1 | 0 | 2009-06-15 | 2013-07-01 |
| 3 | Maicon | 12 | 2 | 0 | 2004-09-08 | 2010-07-02 |
| 4 | Ramires | 10 | 0 | 0 | 2009-06-15 | 2011-08-10 |
| 5 | Fred | 7 | 6 | 0 | 2006-06-18 | 2013-07-01 |
| 6 | Neymar | 6 | 5 | 0 | 2011-08-10 | 2013-07-01 |
| 6 | Thiago Silva | 6 | 0 | 0 | 2011-08-10 | 2013-07-01 |
| 6 | Luiz Gustavo | 6 | 0 | 0 | 2011-08-10 | 2013-07-01 |
| 9 | Marcelo | 5 | 0 | 0 | 2013-06-15 | 2013-07-01 |
| 9 | Oscar | 5 | 0 | 0 | 2013-06-15 | 2013-07-01 |
| 9 | Hulk | 5 | 0 | 0 | 2013-06-15 | 2013-07-01 |
| 9 | David Luiz | 5 | 0 | 0 | 2013-06-15 | 2013-07-01 |
| 9 | Hernanes | 5 | 0 | 0 | 2013-06-15 | 2013-07-01 |
| 14 | Paulinho | 4 | 2 | 0 | 2013-06-15 | 2013-07-01 |
| 15 | Jo | 3 | 2 | 0 | 2013-06-15 | 2013-07-01 |
| 16 | Dante | 2 | 1 | 0 | 2013-06-22 | 2013-06-26 |
| 16 | Bernard | 2 | 0 | 0 | 2013-06-22 | 2013-06-26 |
| 18 | Fernandinho | 1 | 0 | 0 | 2011-08-10 | 2011-08-10 |