| Player | Matches | Goals | Penalties | First match | Last match |
|---|---|---|---|---|---|
| Rüdiger, Antonio | 10 | 1 | 0 | 2012-11-14 | 2014-03-04 |
| Rudy, Sebastian | 23 | 5 | 3 | 2009-09-04 | 2013-06-12 |
| Ruländer, Matthias | 1 | 0 | 0 | 1985-09-24 | 1985-09-24 |
| Rummenigge, Michael | 10 | 4 | 2 | 1983-09-06 | 1985-09-24 |
| Rydlewicz, René | 16 | 3 | 0 | 1992-10-13 | 1996-03-26 |
| Sabiri, Abdelhamid | 5 | 1 | 0 | 2018-10-16 | 2019-03-26 |
| Saborowski, Frank | 4 | 0 | 0 | 1980-06-10 | 1980-06-21 |
| Sahin, Deniz | 3 | 0 | 0 | 1997-11-25 | 1998-04-14 |
| Salger, Stephan | 2 | 0 | 0 | 2010-11-16 | 2011-02-09 |
| Sam, Sidney | 7 | 1 | 0 | 2009-09-08 | 2010-08-11 |
| Samardzic, Lazar | 5 | 2 | 0 | 2022-06-03 | 2022-11-19 |
| Sané, Leroy | 10 | 5 | 0 | 2015-09-03 | 2016-11-15 |
| Sauer, Gunnar | 4 | 0 | 0 | 1987-04-28 | 1987-09-22 |
| Schaaf, Thomas | 2 | 0 | 0 | 1987-11-17 | 1987-12-02 |
| Schade, Kevin | 8 | 4 | 0 | 2021-10-07 | 2023-06-28 |
| Schäfer, Günther | 16 | 0 | 0 | 1981-04-28 | 1984-02-28 |
| Schäper, Tobias | 6 | 0 | 0 | 1999-09-21 | 2000-03-28 |
| Schatzschneider, Dieter | 7 | 2 | 0 | 1980-05-20 | 1981-05-23 |
| Scheike, Michael | 2 | 0 | 0 | 1984-03-27 | 1984-04-17 |
| Scherbe, Jörg | 12 | 0 | 0 | 1997-11-25 | 1999-06-03 |
| Scherhant, Derry | 2 | 0 | 0 | 2025-03-21 | 2025-03-25 |
| Scheuer, Sven | 1 | 0 | 0 | 1990-10-30 | 1990-10-30 |
| Schieber, Julian | 7 | 5 | 0 | 2009-09-04 | 2010-08-11 |
| Schindler, Christopher | 4 | 0 | 0 | 2011-03-25 | 2011-11-15 |
| Schindler, Kevin | 12 | 2 | 0 | 2007-11-16 | 2009-10-13 |
| Schindzielorz, Sebastian | 16 | 1 | 0 | 1999-03-30 | 2001-10-05 |
| Schlaudraff, Jan | 3 | 0 | 0 | 2004-08-17 | 2004-10-12 |
| Schlicke, Björn | 13 | 0 | 0 | 2002-08-20 | 2004-02-17 |
| Schlotterbeck, Nico | 13 | 3 | 0 | 2019-09-05 | 2021-06-06 |
| Schmäler, Nils | 13 | 1 | 0 | 1989-04-25 | 1992-03-23 |
| Schmäler, Olaf | 4 | 0 | 0 | 1990-08-28 | 1991-06-04 |
| Schmelzer, Marcel | 11 | 0 | 0 | 2009-03-31 | 2010-08-11 |
| Schmidt, Dennis | 2 | 0 | 0 | 2009-08-11 | 2009-08-12 |
| Schmidt, Lars | 1 | 0 | 0 | 1985-11-16 | 1985-11-16 |
| Schmidt, Oliver | 13 | 0 | 0 | 1994-09-06 | 1996-03-26 |
| Schmidt, Tan-Kenneth | 4 | 0 | 0 | 2023-03-28 | 2023-10-13 |
| Schmöller, Frank | 1 | 0 | 0 | 1987-04-28 | 1987-04-28 |
| Schneider, Martin | 8 | 1 | 0 | 1988-04-26 | 1990-02-28 |
| Schneider, René | 8 | 1 | 0 | 1995-02-21 | 1996-03-13 |
| Schneider, Theo | 10 | 0 | 0 | 1979-10-10 | 1980-12-02 |
| Schneider, Uwe | 7 | 0 | 0 | 1991-09-10 | 1992-12-22 |
| Scholl, Mehmet | 5 | 3 | 0 | 1991-06-04 | 1992-03-23 |
| Schön, Alfred | 14 | 1 | 0 | 1982-03-23 | 1984-03-27 |
| Schönheim, Fabian | 9 | 0 | 0 | 2006-08-15 | 2008-03-25 |
| Schreml, Uwe | 7 | 0 | 0 | 1980-05-20 | 1980-12-02 |
| Schröder, Michael | 7 | 0 | 0 | 1983-10-04 | 1985-03-26 |
| Schroth, Markus | 20 | 4 | 0 | 1996-03-26 | 1998-05-30 |
| Schubert, Markus | 6 | 0 | 0 | 2018-09-07 | 2019-11-17 |
| Schulz, Christian | 16 | 5 | 1 | 2004-08-17 | 2006-05-28 |
| Schulz, Daniel | 2 | 0 | 0 | 2007-06-02 | 2007-06-04 |