| Player | Matches | Goals | Penalties | First match | Last match |
|---|---|---|---|---|---|
| Schulz, Werner | 4 | 0 | 0 | 1935-04-28 | 1938-03-20 |
| Schulz, Willi | 66 | 0 | 0 | 1959-12-20 | 1970-06-17 |
| Schumacher, Toni | 76 | 0 | 0 | 1979-05-26 | 1986-10-15 |
| Schumann, Georg | 1 | 0 | 0 | 1924-08-31 | 1924-08-31 |
| Schümmelfeder, Josef | 5 | 0 | 0 | 1913-10-26 | 1921-06-05 |
| Schürrle, André | 57 | 22 | 0 | 2010-11-17 | 2017-03-26 |
| Schuster, Bernd | 21 | 4 | 0 | 1979-05-22 | 1984-02-29 |
| Schuster, Dirk | 3 | 0 | 0 | 1994-10-12 | 1995-02-22 |
| Schütz, Franz | 11 | 0 | 0 | 1929-02-10 | 1932-12-04 |
| Schütz, Jürgen | 6 | 2 | 0 | 1960-03-23 | 1963-05-05 |
| Schwabl, Manfred | 4 | 0 | 0 | 1987-09-23 | 1988-04-27 |
| Schwartz, Hans | 2 | 0 | 0 | 1934-05-27 | 1934-10-07 |
| Schwarzenbeck, Georg | 44 | 0 | 0 | 1971-06-12 | 1978-02-22 |
| Schwedler, Willy | 1 | 0 | 0 | 1921-09-18 | 1921-09-18 |
| Schweickert, Hermann | 1 | 0 | 0 | 1909-04-04 | 1909-04-04 |
| Schweinsteiger, Bastian | 121 | 24 | 5 | 2004-06-06 | 2016-08-31 |
| Sebescen, Zoltán | 1 | 0 | 0 | 2000-02-23 | 2000-02-23 |
| Seel, Wolfgang | 6 | 0 | 0 | 1974-09-04 | 1977-12-14 |
| Seeler, Uwe | 72 | 43 | 0 | 1954-10-16 | 1970-09-09 |
| Seiderer, Lony | 8 | 5 | 0 | 1920-06-27 | 1924-04-21 |
| Seliger, Rudolf | 2 | 0 | 0 | 1974-12-22 | 1976-10-06 |
| Serdar, Suat | 4 | 0 | 0 | 2019-10-09 | 2020-09-03 |
| Sesta, Karl | 3 | 0 | 0 | 1941-06-15 | 1942-02-01 |
| Siedl, Gerhard | 6 | 3 | 0 | 1957-04-03 | 1959-12-20 |
| Sieloff, Klaus-Dieter | 14 | 5 | 3 | 1964-06-07 | 1971-06-22 |
| Siemensmeyer, Hans | 3 | 2 | 0 | 1967-09-27 | 1967-11-22 |
| Sievert, Helmut | 1 | 0 | 0 | 1936-09-27 | 1936-09-27 |
| Siffling, Otto | 31 | 17 | 0 | 1934-05-27 | 1938-04-24 |
| Simetsreiter, Willy | 8 | 8 | 0 | 1935-08-25 | 1937-08-29 |
| Sing, Albert | 9 | 1 | 0 | 1940-10-20 | 1942-11-22 |
| Sinkiewicz, Lukas | 3 | 0 | 0 | 2005-09-03 | 2005-10-08 |
| Skoumal, Stefan | 3 | 0 | 0 | 1938-06-09 | 1940-04-14 |
| Sobek, Hanne | 10 | 2 | 0 | 1923-06-03 | 1931-06-21 |
| Sold, Wilhelm | 12 | 0 | 0 | 1935-08-18 | 1942-09-20 |
| Solz, Wolfgang | 2 | 0 | 0 | 1962-10-24 | 1964-04-29 |
| Sonnrein, Heinrich | 2 | 0 | 0 | 1935-09-15 | 1936-03-15 |
| Sorg, Oliver | 1 | 0 | 0 | 2014-05-13 | 2014-05-13 |
| Sorkale, Walter | 1 | 0 | 0 | 1911-10-29 | 1911-10-29 |
| Stach, Anton | 5 | 0 | 0 | 2022-03-26 | 2026-09-27 |
| Stark, Niklas | 2 | 0 | 0 | 2019-11-19 | 2020-10-07 |
| Steffen, Bernhard | 2 | 0 | 0 | 1958-04-02 | 1960-05-11 |
| Steffenhagen, Arno | 1 | 0 | 0 | 1971-09-08 | 1971-09-08 |
| Stein, Erwin | 1 | 1 | 0 | 1959-05-20 | 1959-05-20 |
| Stein, Uli | 6 | 0 | 0 | 1983-06-07 | 1986-05-14 |
| Steiner, Paul | 1 | 0 | 0 | 1990-05-30 | 1990-05-30 |
| Steiner, Rudolf | 1 | 0 | 0 | 1964-05-12 | 1964-05-12 |
| Steinmann, Heinz | 3 | 1 | 0 | 1962-10-24 | 1965-05-12 |
| Stephan, Günter | 1 | 0 | 0 | 1935-08-18 | 1935-08-18 |
| Stielike, Uli | 42 | 3 | 0 | 1975-09-03 | 1984-09-12 |
| Stiller, Angelo | 9 | 0 | 0 | 2024-09-07 | 2026-06-25 |